In client server application you have two different components to test. Application is loaded on server machine while the application exe on every client machine. You will test broadly in categories like, GUI on both sides, functionality, Load, client-server interaction, backend. This environment is mostly used in Intranet networks. You are aware of number of clients and servers and their locations in the test scenario.
Web application is a bit different and complex to test as tester dont have that much control over the application. Application is loaded on the server whose location may or may not be known and no exe is installed on the client machine, you have to test it on different web browsers. Web applications are supposed to be tested on different browsers and OS platforms so broadly Web application is tested mainly for browser compatibility and operating system compatibility, error handling, static pages, backend testing and load testing.
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